Calorific Value (CV) of Waste

The amount of heat released by a unit weight or unit volume of a substance during complete combustion, measured in units of energy per amount of material e.g. kJ/Kg

The CV of the waste depends on the composition of the waste. Waste with a lot of PVC has a higher calorific value then waste with less PVC and more paper. To estimate the calorific value of the waste mix you have, you can make an average on your composition.

How To Calculate The Average Calorific Value Of A Waste Mix

Example

What is the average calorfic value of the waste mix?

We have a waste mix consisting out of 3 fractions; Hazardous waste represents 20% of the mass amount and has a calorific value of 12 MJ/kg. Medical waste represents 50% of the mass amount and has a calorific value of 19 MJ/kg. Plastics - PVC waste represents 30% of the mass amount and has a calorific value of 35 MJ/kg.

Calculation
Calculation of Calorific Value of Waste
Material - fraction CV (MJ/kg) % amount % CV representing in waste mix
Hazardous waste 12 20% 2,4 (=12X0,2)
Medical waste 19 50% 9,5 (=19x0,5)
Plastics - PVC 35 30% 10,5 (=35x0,3)
Total : 22,4(=2,4+9,5+10,5)MJ/kg

Conclusion: the waste mix has an average calorific value of 22,4 MJ/kg

Calorific value (CV): Examples
Here we give some approximate about the calorific value of materials
Type of material CV (MJ/kg) CV (k Cal / kg)
Medical waste 19-24 4540-5735
Industrial & hazardous waste 22-40 5257-9558
Domestic waste (without recycling) 7-16 1673-3823
Domestic waste (after recycling) 10-14 2389-3345
PVC 41 9797
Dry wood 14,4 3441
Paper 13,5 3226
Braun carbon 7-12 1673-2867
Petrol (benzene) 45-47 10573-11231
Coal 15-27 3584-6452
Diesel 46 10992
Ethanol 30 7168

A material can burn without supporting fuel when it has a calorific value of min. 14,4 MJ/kg, this is approximately dry wood. To know the overall calorific value of the waste, you need to measure the calorific value or estimate by analyzing the composition.

If there is no chemical reaction by mixing the different materials together, a weighted average of the different calorific values are good approximate values for the CV of the waste mix.

If the amount of waste is known, and the calorific value of the waste is known, it is possible to design the size of the incinerator and flue gas treatment system.

DECOMPOSING TIME FOR DIFFERNT WASTE

Different sources have different information on the actual time various waste items take to decompose in landfills.

Calorific value (CV): Examples
Here we give some approximate about the calorific value of materials
ITEMS TIME
Cigarette Butts 10-12 years
Monofilament Fishing Line 600 years
Rubber-Boot Sole 50-80 years
Foamed Plastic Cups 50 years
Leather Shoes 25-40 years
Milk Cartons 5 years
Plywood 1-3 years
Painted Board 13 years
Cotton Glove 3 months
Cardboard 2 months
Styrofoam Does not biodegrade
Nylon Fabric 30-40 years
Tin Can 50 years
Ropes 3-14 months
Waxed milk cartons 3 months
Aluminum Cans 200-250 years
Train tickets 2 weeks
Paper Waste 2-6 weeks
Canvas products 1 year
Batteries 100 years
Lumber 10-15 years
Sanitary Pads 500-800 years
Disposale Diapers 250-500 years
Wool Clothing 1-5 years
Tinfoil Does not biodegrade

WHAT IS ACTIVATED CARBON?

Activated carbon has an incredibly large surface area per unit volume, and a network of submicroscopic pores where adsorption takes place. Activated carbon is a material that is produced from carbonaceous source materials, such as coal, coconuts, nutshells, peat, wood, and lignite. The primary raw material used for activated carbon is any organic material with a high carbon content. The carbon-based material is converted to activated carbon through physical modification and thermal decomposition in a furnace, under a controlled atmosphere and temperature. The finished product has a large surface area per unit volume and a network of submicroscopic pores where adsorption takes place.

Activated carbon, also called activated charcoal, is a form of carbon processed to have small, low-volume pores that increase the surface area available for adsorption or chemical reactions. Activated is sometimes substituted with active, Further chemical treatment often enhances adsorption properties. Activated charcoal is a great adsorbent because of it's huge surface area. While it doesn't bind very many ions/ atoms/ molecules per surface area (which is the characteristic of a 'good' adsorbent), due to very big surface area per unit of mass it can absorb a lot of particles. Combustion is a rapid, exothermic reaction between a fuel and oxygen (O2). In incineration applications, the fuel is predominately waste (although fossil fuels may be co-fired) and the oxygen source is air. Combustion produces many of the same stable end products, whether the material burned is natural gas, coal, wood, gasoline, municipal solid waste, hazardous waste, or medical waste. The flame zone of a well designed incinerator is sufficiently hot to break down all organic and many inorganic molecules, allowing reactions between most volatile components of the waste and the oxygen and nitrogen (N2) in air. The predominant reactions are between carbon (C) and oxygen, producing carbon dioxide (CO2), and between hydrogen (H) and oxygen, producing water vapor (H2O). Incomplete combustion of organic compounds in the waste feed stream produces some carbon monoxide (CO) and carbon-containing particles. Hydrogen also reacts with organically-bound chlorine to produce hydrogen chloride (HCl). In addition, many other reactions occur, producing sulfur oxides (SOx) from sulfur compounds, nitrogen oxides (NOx) from nitrogen compounds (and, a little, from the nitrogen in the air), metal oxides from compounds of some metals, and metal vapors from compounds of others

ACTIVATED CARBON - USES

It is used in methane and hydrogen storage, air purification, decaffeination, gold purification, metal extraction, water purification, medicine, sewage treatment, air filters in gas masks and respirators, filters in compressed air, teeth whitening, and many other applications.

MORE ON PLASTICS

The word, plastic, was derived from the word ‘Plastikos’ meaning ‘to mould’ in Greek. It is a material which is largely used because of its convenience and usefulness in daily life

Well-known plastics, and their use
Polyamide (usually called nylon) Women's stockings, gears, car parts, toothbrush bristles
Polycarbonate bulletproof glass, compact discs, DVDs.
Polyethylene tubes, bottles, shopping bags, milk jugs, body armor (made with polyethylene with especially long chains)
Polyethylene terephthalate (called PET when used for bottles, and polyester when used for clothes or other materials)
Polypropylene food containers, chairs
Polystyrene CD cases, plastic cups, plastic forks and knives
Polyurethane rubber, foam, shiny coatings on wood and tile
Polyvinyl chloride (called PVC, usually) pipes (chemicals can make PVC softer for toys and cushions)
MATERIAL MOULD TEMPERATURE
RANGE (℃)
MELT TEMPERATURE
RANGE (℃)
ABS 40-80 190-270
ABS/PC ALLOY 40-80 245-265
ACETAL 50-120 180-210
ACRYLIC 50-80 220-250
CAB 40-50 170-240
HDPE 20-60 210-270
LDPE 20-60 180-240
NYLON 6 40-90 230-290
NYLON 6 (30% GF) 50-90 250-290
NYLON 6/6 40-90 270-300
NYLON 6/6 (33% GF) 40-90 280-300
NYLON 11 40-110 220-250
NYLON 12 40-110 190-200
PEEK 120-160 350-390
POLYCARBONATE 85-120 280-320
POLYESTER PBT 60-90 240-275
PET (SEMI CRYSTALLINE) 20-30 260-280
PET(AMORPHOUS) 20-30 260-280
POLYPROPYLENE (COPOLYMERS) 30-80 200-280
POLYPROPYLENE (HOMOPOLYMERS) 30-80 200-280
POLYPROPYLENE (30% TALC FILLED) 30-50 240-290
POLYPROPYLENE (30% GF) 40-80 250-290
POLYSTYRENE 30-60 170-280
POLYSTYRENE (30% GF) 40-80 250-290
PVC P 20-40 170-190
PVC U 20-60 160-210
SAN 50-85 200-260
SAN (30% GF) 50-70 250-270
TPE 40-70 260-320

Most of the effects of temperature to thermoplastic occur at high heat levels, although excessively low temperatures can have an impact as well. Mechanical properties, chemical resistance, electrical conductivity, material fatigue, and many other attributes can be affected by increased temperatures.

This is to clear and show the fact that all the materials can be toxic when they are un appropriately used and exposed.

Some polymers can emit toxic substance at 120 degrees Celsius and some can withstand 420 degrees with almost zero levels of emitions.

At extreme temperatures polymers will simply burn down very quickly - leaving no toxic materials around.